Wednesday, September 4, 2019

New artifacts suggest people arrived in North America earlier than previously thought








August 30, 2019

Oregon State University

Stone tools and other artifacts unearthed from an archeological dig at the Cooper's Ferry site in western Idaho suggest that people lived in the area 16,000 years ago, more than a thousand years earlier than scientists previously thought.





Stone tools and other artifacts unearthed from an archeological dig at the Cooper's Ferry site in western Idaho suggest that people lived in the area 16,000 years ago, more than a thousand years earlier than scientists previously thought.


The artifacts would be considered among the earliest evidence of people in North America.
The findings, published today in Science, add weight to the hypothesis that initial human migration to the Americas followed a Pacific coastal route rather than through the opening of an inland ice-free corridor, said Loren Davis, a professor of anthropology at Oregon State University and the study's lead author.
"The Cooper's Ferry site is located along the Salmon River, which is a tributary of the larger Columbia River basin. Early peoples moving south along the Pacific coast would have encountered the Columbia River as the first place below the glaciers where they could easily walk and paddle in to North America," Davis said. "Essentially, the Columbia River corridor was the first off-ramp of a Pacific coast migration route.
"The timing and position of the Cooper's Ferry site is consistent with and most easily explained as the result of an early Pacific coastal migration."
Cooper's Ferry, located at the confluence of Rock Creek and the lower Salmon River, is known by the Nez Perce Tribe as an ancient village site named Nipéhe. Today the site is managed by the U.S. Bureau of Land Management.
Davis first began studying Cooper's Ferry as an archaeologist for the BLM in the 1990s. After joining the Oregon State faculty, he partnered with the BLM to establish a summer archaeological field school there, bringing undergraduate and graduate students from Oregon State and elsewhere for eight weeks each summer from 2009 to 2018 to help with the research.
The site includes two dig areas; the published findings are about artifacts found in area A. In the lower part of that area, researchers uncovered several hundred artifacts, including stone tools; charcoal; fire-cracked rock; and bone fragments likely from medium- to large-bodied animals, Davis said. They also found evidence of a fire hearth, a food processing station and other pits created as part of domestic activities at the site.
Over the last two summers, the team of students and researchers reached the lower layers of the site, which, as expected, contained some of the oldest artifacts uncovered, Davis said. He worked with a team of researchers at Oxford University, who were able to successfully radiocarbon date a number of the animal bone fragments.
The results showed many artifacts from the lowest layers are associated with dates in the range of 15,000 to 16,000 years old.
"Prior to getting these radiocarbon ages, the oldest things we'd found dated mostly in the 13,000-year range, and the earliest evidence of people in the Americas had been dated to just before 14,000 years old in a handful of other sites," Davis said. "When I first saw that the lower archaeological layer contained radiocarbon ages older than 14,000 years, I was stunned but skeptical and needed to see those numbers repeated over and over just to be sure they're right. So we ran more radiocarbon dates, and the lower layer consistently dated between 14,000-16,000 years old."
The dates from the oldest artifacts challenge the long-held "Clovis First" theory of early migration to the Americas, which suggested that people crossed from Siberia into North America and traveled down through an opening in the ice sheet near the present-day Dakotas. The ice-free corridor is hypothesized to have opened as early as 14,800 years ago, well after the date of the oldest artifacts found at Cooper's Ferry, Davis said.
"Now we have good evidence that people were in Idaho before that corridor opened," he said. "This evidence leads us to conclude that early peoples moved south of continental ice sheets along the Pacific coast."
Davis's team also found tooth fragments from an extinct form of horse known to have lived in North America at the end of the last glacial period. These tooth fragments, along with the radiocarbon dating, show that Cooper's Ferry is the oldest radiocarbon-dated site in North America that includes artifacts associated with the bones of extinct animals, Davis said.
The oldest artifacts uncovered at Cooper's Ferry also are very similar in form to older artifacts found in northeastern Asia, and particularly, Japan, Davis said. He is now collaborating with Japanese researchers to do further comparisons of artifacts from Japan, Russia and Cooper's Ferry. He is also awaiting carbon-dating information from artifacts from a second dig location at the Cooper's Ferry site.
"We have 10 years' worth of excavated artifacts and samples to analyze," Davis said. "We anticipate we'll make other exciting discoveries as we continue to study the artifacts and samples from our excavations."
Co-authors of the paper include David Sisson, an archaeologist with the BLM; David Madsen of the University of Texas at Austin; Lorena Becerra Valdivia and Thomas Higham of the Oxford University radiocarbon accelerator unit; and other researchers in the U.S., Japan and Canada. The research was funded in part by the Keystone Archaeological Research Fund and the Bernice Peltier Huber Charitable Trust.


Story Source:
Materials provided by Oregon State University. Original written by Michelle Klampe. Note: Content may be edited for style and length.

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Journal Reference:
Loren G. Davis, et al. Late Upper Paleolithic occupation at Cooper’s Ferry, Idaho, USA, ~16,000 years ago. Science, Aug 30th, 2019 DOI: 10.1126/science.aax9830

Cite This Page:
Oregon State University. "New artifacts suggest people arrived in North America earlier than previously thought." ScienceDaily. ScienceDaily, 30 August 2019. .


Suggested move to plant-based diets risks worsening brain health nutrient deficiency









And UK failing to recommend or monitor dietary levels of choline, warns nutritionist

August 29, 2019

BMJ

The momentum behind a move to plant-based and vegan diets for the good of the planet is commendable, but risks worsening an already low intake of an essential nutrient involved in brain health, warns a nutritionist.






The momentum behind a move to plant-based and vegan diets for the good of the planet is commendable, but risks worsening an already low intake of an essential nutrient involved in brain health, warns a nutritionist in the online journal BMJ Nutrition, Prevention & Health.


To make matters worse, the UK government has failed to recommend or monitor dietary levels of this nutrient -- choline -- found predominantly in animal foods, says Dr Emma Derbyshire, of Nutritional Insight, a consultancy specialising in nutrition and biomedical science.
Choline is an essential dietary nutrient, but the amount produced by the liver is not enough to meet the requirements of the human body.
Choline is critical to brain health, particularly during fetal development. It also influences liver function, with shortfalls linked to irregularities in blood fat metabolism as well as excess free radical cellular damage, writes Dr Derbyshire.
The primary sources of dietary choline are found in beef, eggs, dairy products, fish, and chicken, with much lower levels found in nuts, beans, and cruciferous vegetables, such as broccoli.
In 1998, recognising the importance of choline, the US Institute of Medicine recommended minimum daily intakes. These range from 425 mg/day for women to 550 mg/day for men, and 450 mg/day and 550 mg/day for pregnant and breastfeeding women, respectively, because of the critical role the nutrient has in fetal development.
In 2016, the European Food Safety Authority published similar daily requirements. Yet national dietary surveys in North America, Australia, and Europe show that habitual choline intake, on average, falls short of these recommendations.
"This is....concerning given that current trends appear to be towards meat reduction and plant-based diets," says Dr Derbyshire.
She commends the first report (EAT-Lancet) to compile a healthy food plan based on promoting environmental sustainability, but suggests that the restricted intakes of whole milk, eggs and animal protein it recommends could affect choline intake.
And she is at a loss to understand why choline does not feature in UK dietary guidance or national population monitoring data.
"Given the important physiological roles of choline and authorisation of certain health claims, it is questionable why choline has been overlooked for so long in the UK," she writes. "Choline is presently excluded from UK food composition databases, major dietary surveys, and dietary guidelines," she adds.
It may be time for the UK government's independent Scientific Advisory Committee on Nutrition to reverse this, she suggests, particularly given the mounting evidence on the importance of choline to human health and growing concerns about the sustainability of the planet's food production.
"More needs to be done to educate healthcare professionals and consumers about the importance of a choline-rich diet, and how to achieve this," she writes.
"If choline is not obtained in the levels needed from dietary sources per se then supplementation strategies will be required, especially in relation to key stages of the life cycle, such as pregnancy, when choline intakes are critical to infant development," she concludes.


Story Source:
Materials provided by BMJ. Note: Content may be edited for style and length.

Journal Reference:
Emma Derbyshire. Could we be overlooking a potential choline crisis in the United Kingdom? BMJ Nutrition, Prevention & Health, 2019; bmjnph-2019-000037 DOI: 10.1136/bmjnph-2019-000037





Reactor turns greenhouse gas into pure liquid fuel










Lab's 'green' invention reduces carbon dioxide into valuable fuels


September 3, 2019

Rice University

An electrocatalysis reactor built at Rice University recycles carbon dioxide to produce pure liquid fuel solutions using electricity. The scientists behind the invention hope it will become an efficient and profitable way to reuse the greenhouse gas and keep it out of the atmosphere.



A common greenhouse gas could be repurposed in an efficient and environmentally friendly way with an electrolyzer that uses renewable electricity to produce pure liquid fuels.


The catalytic reactor developed by the Rice University lab of chemical and biomolecular engineer Haotian Wang uses carbon dioxide as its feedstock and, in its latest prototype, produces highly purified and high concentrations of formic acid.
Formic acid produced by traditional carbon dioxide devices needs costly and energy-intensive purification steps, Wang said. The direct production of pure formic acid solutions will help to promote commercial carbon dioxide conversion technologies.
The method is detailed in Nature Energy.
Wang, who joined Rice's Brown School of Engineering in January, and his group pursue technologies that turn greenhouse gases into useful products. In tests, the new electrocatalyst reached an energy conversion efficiency of about 42%. That means nearly half of the electrical energy can be stored in formic acid as liquid fuel.
"Formic acid is an energy carrier," Wang said. "It's a fuel-cell fuel that can generate electricity and emit carbon dioxide -- which you can grab and recycle again.
"It's also fundamental in the chemical engineering industry as a feedstock for other chemicals, and a storage material for hydrogen that can hold nearly 1,000 times the energy of the same volume of hydrogen gas, which is difficult to compress," he said. "That's currently a big challenge for hydrogen fuel-cell cars."
Two advances made the new device possible, said lead author and Rice postdoctoral researcher Chuan Xia. The first was his development of a robust, two-dimensional bismuth catalyst and the second a solid-state electrolyte that eliminates the need for salt as part of the reaction.
"Bismuth is a very heavy atom, compared to transition metals like copper, iron or cobalt," Wang said. "Its mobility is much lower, particularly under reaction conditions. So that stabilizes the catalyst." He noted the reactor is structured to keep water from contacting the catalyst, which also helps preserve it.
Xia can make the nanomaterials in bulk. "Currently, people produce catalysts on the milligram or gram scales," he said. "We developed a way to produce them at the kilogram scale. That will make our process easier to scale up for industry."
The polymer-based solid electrolyte is coated with sulfonic acid ligands to conduct positive charge or amino functional groups to conduct negative ions. "Usually people reduce carbon dioxide in a traditional liquid electrolyte like salty water," Wang said. "You want the electricity to be conducted, but pure water electrolyte is too resistant. You need to add salts like sodium chloride or potassium bicarbonate so that ions can move freely in water.
"But when you generate formic acid that way, it mixes with the salts," he said. "For a majority of applications you have to remove the salts from the end product, which takes a lot of energy and cost. So we employed solid electrolytes that conduct protons and can be made of insoluble polymers or inorganic compounds, eliminating the need for salts."
The rate at which water flows through the product chamber determines the concentration of the solution. Slow throughput with the current setup produces a solution that is nearly 30% formic acid by weight, while faster flows allow the concentration to be customized. The researchers expect to achieve higher concentrations from next-generation reactors that accept gas flow to bring out pure formic acid vapors.
The Rice lab worked with Brookhaven National Laboratory to view the process in progress. "X-ray absorption spectroscopy, a powerful technique available at the Inner Shell Spectroscopy (ISS) beamline at Brookhaven Lab's National Synchrotron Light Source II, enables us to probe the electronic structure of electrocatalysts in operando -- that is, during the actual chemical process," said co-author Eli Stavitski, lead beamline scientist at ISS. "In this work, we followed bismuth's oxidation states at different potentials and were able to identify the catalyst's active state during carbon dioxide reduction."
With its current reactor, the lab generated formic acid continuously for 100 hours with negligible degradation of the reactor's components, including the nanoscale catalysts. Wang suggested the reactor could be easily retooled to produce such higher-value products as acetic acid, ethanol or propanol fuels.
"The big picture is that carbon dioxide reduction is very important for its effect on global warming as well as for green chemical synthesis," Wang said. "If the electricity comes from renewable sources like the sun or wind, we can create a loop that turns carbon dioxide into something important without emitting more of it."
Co-authors are Rice graduate student Peng Zhu; graduate student Qiu Jiang and Husam Alshareef, a professor of material science and engineering, at King Abdullah University of Science and Technology, Saudi Arabia (KAUST); postdoctoral researcher Ying Pan of Harvard University; and staff scientist Wentao Liang of Northeastern University. Wang is the William Marsh Rice Trustee Assistant Professor of Chemical and Biomolecular Engineering. Xia is a J. Evans Attwell-Welch Postdoctoral Fellow at Rice.
Rice and the U.S. Department of Energy Office of Science User Facilities supported the research.


Story Source:
Materials provided by Rice University. Note: Content may be edited for style and length.

Journal Reference:
Chuan Xia, Peng Zhu, Qiu Jiang, Ying Pan, Wentao Liang, Eli Stavitsk, Husam N. Alshareef, Haotian Wang. Continuous production of pure liquid fuel solutions via electrocatalytic CO2 reduction using solid-electrolyte devices. Nature Energy, 2019; DOI: 10.1038/s41560-019-0451-x























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